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MEND - Mine Environment Neutral Drainage at CANMET-MMSL

Geochemical Assessment of the Equity Silver Tailings Pond

Mine Environment Neutral Drainage at CANMET-MMSL

MEND Report 2.11.5c
August 1996

EXECUTIVE SUMMARY

A geochemical survey was performed on the Equity Silver Tailings Pond near Houston, B.C. in the fall of 1995. Replicate peepers were used to collect pore waters from each of a shallow (~1 m) and deep site (~5 m) within the tailings pond. Ancillary solid-phase and water column data were also collected.

The distributions of most elements is indicative of small-scale, lateral inhomogeneity. While dissolved Cu is neither released nor consumed by the tailings, Sb and As display opposing fluxes. Arsenic is released from pore waters to pond waters at both sites in all replicates via dissolution of an unidentified solid phase. Conversely, Sb is consumed rapidly within the surfical deposits, presumably by adsorption to an existing solid-phase.

Direct determinations of tailings oxidation rates were calculated by measurements of dissolved oxygen from the peepers cells across the sediment-water interface. Dissolved oxygen fluxes were determined by the application of Fick’s law of diffusion across the interface and also through a diffusion-consumption model applied to the dissolved oxygen data in the pore waters. The tailings oxidation rate (assuming the entire oxygen flux was consumed by tailings oxidation) was within the range of values seen for other subaqueous tailings deposits.


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