STUDY ON
METALS RECOVERY/RECYCLING FROM ACID MINE DRAINAGE
Mine Environment Neutral Drainage at CANMET-MMSL |
MEND Project
3.21.1(a)
July 1991
EXECUTIVE
SUMMARY
Removal and
recycling of metal contaminants and other by-products from acid
mine drainage is the subject of this Mine Environment Neutral
Drainage (MEND) project. Critical literature surveys and investigations
in several selected research alternatives such as chemical treatment
(that is modifications to lime neutralization), solvent extraction,
ion exchange, bioadsorption and electrowinning, are aimed at the
development of a viable treatment process. The technical and economic
feasibility of the techniques will be evaluated, in search of a
process that produces a high quality effluent, secures a satisfactory
revenue and minimizes/eliminates hazardous sludge production.
A literature
review was carried out by CANMET scientists from four different
disciplines in the field of metals and/or by-products recovery from
acid mine drainage effluents. Existing expertise from the application
of these technologies in related fields in mineral processing, as
well as preliminary results from investigations with acid mine drainage
have been utilized to evaluate selected publications and to determine
the most promising process approaches. A preliminary compilation
of data for acid mine drainage in Canada has been made, with particular
interest in high metal concentrations.
Discussion
provided in this report supports the opinion that the recovery of
metals and/or by-products from acid mine drainage is a promising
treatment approach from a technical, economical and environmental
point of view. Detailed laboratory investigations should follow
to study the recovery of various by-products, to develop a treatment
process flowsheet and to evaluate the economical and environmental
benefits. Chemical precipitation and selective ion exchange are
the two most promising technologies for metals removal from acid
mine drainage.
Supplementary
Report
The literature
review carried out in the main report revealed numerous processes
to recover valuable metals from dilute acidic solutions. These processes
should be evaluated for their applicability to acid mine drainage.
There was a request to supplement the work by focusing on specific
contaminants (i.e., Cu. Fe, Ni, Zn), critically assess the published
techniques, offer specific recommendations and propose a focused
research.
The criteria
utilized in this supplemental evaluation were:
- the specific
metals;
- economics;
- technical
feasibility; and
- treated
effluent quality.
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