EVALUATION
OF AN UNDERWATER MONITORING PROBE FOR LOCATING AND ESTIMATING
THE IMPACT OF GROUNDWATER DISCHARGES TO SURFACE WATERS ADJACENT
TO POTENTIAL SOURCES OF ACID MINE DRAINAGE
Mine Environment Neutral Drainage at CANMET-MMSL |
MEND Report
4.8.2
September 1994
EXECUTIVE
SUMMARY
The migration
of leachate from mining operations through the ground is an issue
of concern to the mining industry, regulators, and public, particularly
where leachate constituents may be moving into surface waters. In
many geologic settings, seepage enters surface water invisibly through
submerged fractures and bottom sediments. Until now there were no
practical methods for identifying these subsurface flows. Knowing
the location and contaminant flux of offsite seepage can be important
in estimating the degree of contamination in an area, and in designing
programs for useful monitoring, remediation and reclamation. By
identifying and quantifying subaqueous seeps, it should be possible
to reduce costs of hydrogeological investigation and monitoring.
A new reconnaissance
method for detection of acid mine drainge (AMD) has been evaluated
near mine operations near Sudbury and Timmins, Ontario. An electrical-conductance,
bottom-contacting probe (known as the sediment probe) was towed
behind a slowly moving boat over more than 21 line-kilometres of
lake and river bottom.
The evaluation
has been successful, both as a test of the method and as a preliminary
identification of groundwater discharge areas at the two study sites.
The method effectively solves the problem of identifying discharge
of AMD in surface waters and, by quantifying the groundwater and
solute-transport, it has provided estimates of impact at points
of discharge.
The sediment-probe
method depends on two conditions: 1) groundwater-contaminant plumes
and surface waters differ in electrical conductivity, and 2) upward
advection moves the groundwater signatures within centimetres of
receiving surface waters.
The method
was used to locate eight areas of leachate discharge. These were
studied quantitatively, to evaluate the utility of the probe and
provide site-specific information. Some targets were confirmed by
measuring the porewater electrical conductivity 20 to 120 cm below
the sediment/water interface. Other targets were confirmed using
direct measurements of flux, using seepage meters. Still others
were confirmed by measuring upward gradient, moderately high hydraulic
conductivity and solute chemistry.
The discharge
conductivities ranged from l2 820 to 43 mS/cm and from 6.9 to 4.8
pH. Some discharges contributed nickel in concentration ranging
as high as 9.5 ppm to the surface waters.
In order to
attribute many of the discharges to leachate from mine tailings,
waste rock, septic tanks or road salt, it will be necessary to do
additional chemical and isotopic work using the existing piezometers.
The authors and industrial partners hope to conduct major-ion, metal
and isotopic analyses, to distinguish sources and provide contaminant
concentrations for better flux estimates.
Specific findings:
1. Sediment-probe
results, supported by quantitative measurements, show that groundwater
of elevated electrical conductivity is entering Lake Kamiskotia
along two-thirds, or 1.5 km, of the northeastern shoreline. This
shoreline discharge could contain AMD, road salt, septic-tank effluent
or waters that are naturally high in dissolved solids.
2. Bottom-water
samples below the outlet of Lake Kamiskotia in the Little Kamiskotia
River indicate that AMD may be entering the river 300 m upstream
of any obvious damage to the terrestrial environment.
3. Several
sources of nickel input to the Onaping River were identified on
the river bed. At one location, a crude but illustrative calculation
showed that 12 kilograms of nickel enter the river each year over
a 50 m2 bottom area.
4. Recommendations
for further work include: (a) analysis of existing samples to determine
sources of high dissolved solids water entering the studied surface
waters, and (b) collection of additional samples for chemical and
isotopic analyses. Helium-3/tritium analysis using mass spectrometry
should be used to determine the groundwater residence time for the
discharging waters. Some of the suspected AMD may, in fact, be natural
discharge.
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