Refrigerants and the Ozone Layer
January 1997
Introduction
While Alberta's air quality ranks among the best in the world, we
believe it is our shared responsibility to keep Alberta's air clean.
This brochure provides citizens with information on how Alberta's Environmental
Protection and Enhancement Act helps protect the ozone layer.
The Ozone Layer
Ozone is a natural and vital gas in the upper atmosphere, about 15-40
kilometres above the earth. It varies in thickness and shields the earth
from the sun's harmful ultraviolet (UV) rays.
Scientists have discovered that this natural protective shield is
thinning, causing greater amounts of ultraviolet radiation to reach the
earth's surface. Ultraviolet rays (UVA and UVB) are associated with
sunburns, skin cancer, weakening of the immune system and other physical
ailments such as cataracts. Increased exposure poses a threat to human
health, wildlife, vegetation and crop production. Documented evidence
shows that increased UVB radiation affects wheat, rice, corn, soybeans
and other agricultural crops.
Governments and industries are taking action to reduce the emission
of chemicals that destroy the ozone layer. The Government of Alberta is
participating in a national program to phase out the manufacture and
importation of chlorofluorocarbons (CFCs) by the end of 1995.
Chlorofluorocarbons
Substances like chlorofluorocarbons are extremely stable, synthetic
chemical compounds that contain chlorine, fluorine and carbon. They were
developed in the 1930s as a substitute for ammonia refrigerants.
CFCs are used in various applications because they are nontoxic,
nonflammable and relatively inexpensive to produce. They are primarily
used as a refrigerant for domestic refrigerators and for producing foam
cushioning, insulation, solvents and sterilants. However, when CFCs are
released into the air, these gases travel slowly upward and break down
the ozone layer.
Canada banned CFCs as a propellant in aerosol cans in the 1980s,
reducing their direct release into the atmosphere. As of January 1,
1996, no CFCs may be produced or imported into Canada. Alternative
compounds are being developed to replace CFCs.
Hydrochlorofluorocarbons
Hydrochlorofluorocarbons (HCFCs) are chemical compounds related to
CFCs. This makes HCFCs less stable and about 95 percent less damaging to
the ozone layer. They are mainly used as refrigerant in domestic air
conditioning systems and in manufacturing plastic, insulation and
packaging.
Because HCFCs do contribute to ozone depletion, Canada is phasing out
the production and use of HCFCs between the years 2010-2020. Therefore,
HCFCs should only be used as a short-term alternative replacing CFCs.
Provincial Action to Reduce CFC Emissions
In 1993, the Alberta government passed legislation to prohibit the
release of ozone-depleting substances such as CFCs, HCFCs and Halons.
Provincial regulations require all persons servicing air conditioning or
refrigeration equipment to be certified in accordance with the
Apprenticeship and Industries Training Act and the associated
regulations.
All persons servicing refrigeration or air conditioning equipment
containing CFCs or HCFCs are required to conduct servicing procedures in
accordance with the federal "Code of Practice". Anyone who
commits an unauthorized release of greater than 10 kilograms of an
ozone-depleting substance to the ambient air must report that release to
the Pollution Control Program by calling 1-800-222-6514. Failure to
report an unauthorized release is also an offence under the Alberta Environmental
Protection and Enhancement Act.
Household Refrigerators and Air Conditioning Units
Most household refrigerators contain a chlorofluorocarbon
refrigerant, sometimes called CFC-12 or R-12. While units manufactured
prior to 1993 can contain CFCs or HCFCs, new refrigerators manufactured
after 1993 can contain an alternate refrigerant with lower or
nonexistent ozone-depleting potential. Alternate refrigerants are
continuously being developed. Labels attached to all household units
should list the refrigerant being used.
Refrigerators and air conditioning units are sealed systems. This
means they contain refrigerants within their components as they
function. Units will not normally emit refrigerants unless there is a
leak. If your appliance is not functioning properly, this may indicate a
leak. Have your unit serviced by a qualified technician.
How CFCs and HCFCs Damage the Ozone Layer
Both CFCs and HCFCs can deplete the ozone layer. When released into
the air intentionally or unintentionally, they slowly rise into the
atmosphere. Between 15-40 kilometres above the earth's surface, the
sun's ultraviolet rays break down the CFC and HCFC molecules. This
creates a harmful chlorine by-product (chlorine monoxide), which can
destroy ozone molecules. Each chlorine molecules can destroy tens of
thousands of ozone molecules. These chlorine molecules can remain in the
ozone layer causing damage for 60-400 years.
Consumer Information
As a consumer of refrigeration or air conditioning services, it is
important to be aware of changing legislative requirements and
activities designed to minimize ozone depletion.
The following points will help you to assess your service personnel's
performance and your own responsibility to minimize ozone layer
depletion.
- In Alberta, the "general prohibition on release"
requires that no person shall release or permit the release into the
ambient air of any ozone-depleting substance unless authorized
pursuant to the Regulations.
- In Alberta, in order to comply with the "general prohibition
release", it is mandatory for persons installing, removing,
servicing, repairing, charging or recharging air conditioning
systems, refrigeration equipment or fire extinguishing systems, to
recover or recycle any ozone-depleting substance. Service personnel
must have operational equipment or apparatus capable of servicing
and containing ozone-depleting substances available at the job site.
It is improper for service personnel to just "top up" or
only "add refrigerant", unless the unit has first been
repaired.
- Check your service bill to ensure that service personnel have
checked for leaks. Only qualified service personnel are allowed to
service air conditioning and refrigeration systems.
- Where and when available, choose products that contain alternate
or low ozone-depleting substances.
- All used appliances going to salvage must have the refrigerants
removed prior to final disposal.
- If your car has air conditioning, have it checked periodically to
prevent seal damage. A certified technician can check for leaks with
an electronic leak detector. The preferred method of leak testing
involves removing and recovering refrigerant, pressurizing the
system with dry nitrogen and then recharging the system with
refrigerant.
For more information, please call:
Alberta Environment
Air and Water Approvals Division
(780) 427-5883
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