Composition of the Atmosphere
The atmosphere is a mixture of invisible gases, completely
surrounding the Earth. The most important of these gases are:
- Nitrogen: 78,09%
- Oxygen: 20,95 %
- Water Vapeur: 0 to 3 %
- Carbon dioxine: 0,03 %
- Ozone: 0,000003 %
Although nitrogen and oxygen are the most significant in
terms of quantity, it is actually the very small proportions of water vapour and carbon
dioxide that most influence the behaviour of the atmosphere.
Carbon dioxide has a strong impact on climate, but water
vapour determines weather conditions.
Water vapour causes clouds, fog and precipitation, simply
because of its inherent instability. Depending on temperature and pressure, it varies
between a vapour, liquid and solid.
Obviously, the atmosphere is more than just water vapour.
Indeed, it also contains billions of tonnes of gas and various particles from human
activities and natural phenomena.
In the lower levels, especially in the troposphere, which
is the atmospheric layer in which we live and move about, there are considerable
quantities of liquid or solid particles in suspension, known as aerosols.
Water vapour condenses on aerosols of liquid particles to
form droplets, clouds and fog.
Ice crystals form mainly around aerosols of solid
particles, consisting mostly of dust, pollen, ash, smoke, sea salt and sand, to form
clouds or ice fog.
Aerosols are also responsible for haze and smog, and are
the main triggers of changes in state of water vapour.
Extent of the Atmosphere
The farther we travel from the Earth's surface, the
thinner the air becomes, until it almost disappears. In fact, 99% of the total mass of the
atmosphere lies within 30 km (100,000 feet) of the ground, while fully half of it is
within the first 5.5 km (18,000 feet).
But the trails left by some satellites tell us that it
extends up to some 1600 km above the Earth. Indeed, the aurora borealis can often be seen
at an altitude of over 1000 km.
Although data collected at very high altitudes are not used
in the preparation of day-to-day forecasts, their study is important for an overall
understanding of weather.
Properties of the Atmosphere
Air is inert, fluid, viscous, expansible and compressible,
and as such is subject to the laws of thermodynamics.
Inertia Since air is inert and has mass, some force
is necessary to set it in motion, accelerate or stop it.
The density of air varies considerably from one point to
another. At sea level, it is about 1.125 grams per litre, whereas at 10 km (33,000 feet),
it is only about 0.414 grams per litre.
Fluidity The atmosphere is also highly fluid; it
tends to take up all available space and to exert pressure on all the bodies it surrounds.
Viscosity The air's viscosity is an important
property. Although it allows the air to move and to influence the movements of
neighbouring layers, this same property prevents excessive wind shear.
The movement caused by this viscosity is always slowed by a
much more inert body, however: the obstacles making up the Earth's surface and the
friction they exert.
Expansibility and compressibility As soon as the
pressure of an air mass at some point increases in relation to the surrounding pressure,
the air in question expands and tends to take up more room.
If the surrounding pressure increases, however, the air
mass will decrease in volume as it is compressed.
Thermodynamics Air is as thermodynamic as all other
gases, under the effects of pressure and temperature.
In absolute terms, we know that as soon as a small quantity
of air rises above the surface, its pressure and temperature fall and its volume
increases.
On the other hand, air descending toward the surface
obviously undergoes the opposite changes: it is compressed, its volume shrinks and its
temperature rises.
This phenomenon is not the main cause of atmospheric
warming or cooling, but does play a crucial role in cloud formation due to vertical air
movements.
![Expension and compression of the air with the temperature](/web/20061210003604im_/http://www.qc.ec.gc.ca/meteo/images/Fig_1-1.jpg)
Figure 1 On the left, rising air expands and cools
as its pressure falls. On the right, descending air is compressed and warms, which
increases its pressure.
Divisions of the Atmosphere
Scientists agree on major divisions of the atmosphere,
but the exact dividing lines and characteristics vary with different disciplines and
purposes.
We will discuss two classifications: those of the International
Union of Geodesy and Geophysics (IUGG) and that of Goody, based on temperature
and ionization.
In meteorology, the IUGG system is used, because it divides
the atmosphere into layers according to their thermal structures.
The IUGG system consists of the following layers, by
distance from the surface:
- troposphere
- stratosphere
- mesosphere
- thermosphere
To identify each of the transition zones, the suffix sphere
is simply replaced with pause, to give:
- tropopause
- stratopause
- mesopause
- thermopause
![Systems for dividing the atmosphere into
layers](/web/20061210003604im_/http://www.qc.ec.gc.ca/meteo/images/Fig_1-2_a.jpg)
Figure 2 Systems for dividing the atmosphere into layers.
Troposphere It is in this first layer that the
atmosphere, in contact with the Earth, is the warmest. The Earth's surface captures
the Sun's rays and becomes a radiating body that warms the air, setting it in motion
by simple thermodynamic action.
This produces large-scale rising air currents that warm the
upper levels, while moving gigantic volumes of air horizontally. These movements are what
we call weather systems.
As a result, most weather activity occurs in this lowermost
layer of the atmosphere, the great variety of phenomena that affect us from day to day all
around the world.
The intense concentration of water vapour, associated with
strong rising air currents, leads to clouds and precipitation, thunderstorms, hurricanes
and tornadoes.
Just below the tropopause, the shear caused by the strong
contrast between the troposphere and stratosphere generate the very powerful winds called
jet streams, and gives them their sometimes complex structures.
These narrow and powerful streams of air, which originate
only in the north of the Northern Hemisphere, are so influential that they are part of
what is called the general circulation, that is the trajectory of the Earth's air
masses.
Tropopause The first thermal boundary. The
tropopause marks the end of the biosphere and is the coldest part of the lower atmosphere.
The average altitude of this layer is about 11 km (36,000
feet). Above the poles, it is about 8 km (26,000 feet) from the surface, while at the
equator is at about 18 km (59,000 feet).
The tropopause shifts according to temperature and is
highest in summer. It changes altitude abruptly near the jet streams.
Stratosphere The stratosphere is a 15 km, 50 000
feet layer where the temperature increases gradually to 0° C or even as much as 10° C.
In this layer there is almost no water vapour, and no major
vertical air currents. Occasionally some mother-of-pearl clouds formed from the rare ice
crystals at this level can be seen.
The main characteristic of the stratosphere is the
ultraviolet shield it containsthe ozone layer. Stratospheric warming occurs as this
layer absorbs part of the ultraviolet rays from the Sun.
Stratopause At the top of the stratosphere lies the
stratopause. Past this level, the temperature begins falling again as the ozone becomes
increasingly thinner with height.
Mesosphere The only significant characteristic of
this layer is the rarity of ozone and consequently its absolute minimum temperature of
about -80° C, recorded at a distance of 80 to 90 km from the Earth's surface. This
is the lowest temperature ever recorded in the atmosphere.
It is also in this layer that meteorites burn up as they
come into contact with the atmosphere.
Mesopause The mesopause is another thermal
transition layer; after this point the atmosphere again begins warming with altitude.
Thermosphere Air molecules are rare in this layer,
which is why the Sun's rays strike with such force and temperatures can theoretically
rise to enormous levels.
Exosphere According to the GOODY classification,
this upper part of the atmosphere is where particles begin escaping from the Earth's
pull, and are subject to atomic and molecular exchanges with solar and cosmic particles.
The exosphere is where the aurora borealis occur.
The bottom of the exosphere is not very clearly defined,
but is estimated to lie 500 to 800 km from the Earth's surface.
The International Civil Aviation Organization (ICAO) Standard Atmosphere
The wealth of direct observational data available for the
first 20 km of the atmosphere make it possible to prepare detailed descriptions of average
conditions within this layer.
These data are organized into standard atmospheres,
defined on the basis of average altitude, pressure and temperature conditions at 40°
north latitude.
![Pressure falls with height](/web/20061210003604im_/http://www.qc.ec.gc.ca/meteo/images/Fig_1-3_a.jpg)
Figure 3 ICAO standard atmosphere. Pressure falls
with height, particularly in the lower altitudes.
Some of the values of particular significance are:
- mean sea level (MSL) pressure: 1013.25 hectopascals (hPa or
mb)
- mean sea level temperature: 15 ° C
- rate of decrease of temperature with height (lapse rate) in
the troposphere: 6.5° C per kilometre (1.98° C per 1000 feet)
- height of the tropopause: 11 kilometres (36,000 feet) above
mean sea level
- temperature of the tropopause: -56.5° C
- temperature is constant from the tropopause to the top of
the standard atmosphere.