Retour à la description de la base de données
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* M S D S *
* *
* Canadian Centre for Occupational Health and Safety *
* * * * * * * * * * * * * * * Issue : 99-2 (May, 1999) *
*** IDENTIFICATION ***
MSDS RECORD NUMBER : 1966809
PRODUCT NAME(S) : PERFORMAX* 8471
PRODUCT IDENTIFICATION : Product Number: PFX8471
DATE OF MSDS : 1999-03-05
CURRENCY NOTE : This MSDS was provided to CCOHS in
electronic form on 1999-03-31
*** MANUFACTURER INFORMATION ***
MANUFACTURER : B F Goodrich
ADDRESS : 9911 Brecksville Road
Cleveland Ohio
U.S.A. 44141-3247
Telephone: 800-331-1144 216-447-5000
EMERGENCY TELEPHONE NO. : 800-424-9300 (CHEMTREC, 24 Hour)
*** SUPPLIER/DISTRIBUTOR INFORMATION ***
SUPPLIER/DISTRIBUTOR : Goodrich Canada Inc
ADDRESS : 100 Regina Street South, Suite 360
Waterloo Ontario
Canada N2J 4P9
Telephone: 519-888-3330
Télécopieur : 519-888-3337
EMERGENCY TELEPHONE NO. : 613-996-6666 (CANUTEC, Transportation,
Canada)
800-424-9300 (CHEMTREC, Transportation,
USA)
*** MATERIAL SAFETY DATA ***
MATERIAL SAFETY DATA SHEET
Product Name: PERFORMAX* 8471
Document: PFX8471 CFLN: AUUS
Effective Date: 05 March 1999 Page Number: 1/9
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_______ 1. PRODUCT AND COMPANY IDENTIFICATION _______
Product Name PERFORMAX* 8471
Company Identification BFGoodrich
Performance Materials
9911 Brecksville Rd.
Cleveland, OH 44141-3247
Telephone (800) 331-1144 / (216) 447-5000
Chemtrec (24 Hour) (800) 424-9300
Preparer Health, Safety, and Environmental Department
Product Description Flame retarding aqueous dispersion.
_______ 2. COMPOSITION, INFORMATION ON INGREDIENTS _______
--Ingredient-- -CAS Number- ---%---
Water 0007732-18-5 < 46
Polymer/Solids Proprietary 39
Antimony oxide 0001309-64-4 < 7.9
Decabromodiphenyl oxide 0001163-19-5 7.7
Formaldehyde 0000050-00-0 < 0.060
Notes:
Amounts specified are typical and do not represent a specification.
_______ 3. HAZARDS IDENTIFICATION _______
Acute Health Effects
Repeated or prolonged skin contact may cause irritation.
Vapors or direct eye contact may cause irritation.
Ingestion may cause irritation.
Inhalation may cause irritation of the respiratory tract and mucous
membranes.
FORMALDEHYDE: Vapors may cause eye, nose, and throat irritation at
levels below the STEL for some people. These symptoms are more
noticeable as airborne concentrations increase.
Chronic Health Effects
FORMALDEHYDE: Prolonged,excessive, or repeated exposure to
formaldehyde or solutions containing formaldehyde may cause an
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MATERIAL SAFETY DATA SHEET
Product Name: PERFORMAX* 8471
Document: PFX8471 CFLN: AUUS
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allergic skin reaction and/or respiratory disorders (sensitization).
Signs/Symptoms of Exposure
Irritation.
Routes of Exposure/Entry
Eyes, skin contact, inhalation, ingestion.
Target Organs
Eyes, respiratory tract, skin.
Medical Conditions Aggravated by Exposure
Pre-existing skin problems may be aggravated by prolonged or repeated
contact.
Persons with sensitive airways (e.g., asthmatics) may react to
vapors.
Carcinogenic Status
FORMALDEHYDE: IARC - Group 2A; NTP - Anticipated human carcinogen;
OSHA - Regulated as a carcinogen; ACGIH - A2.
ANTIMONY TRIOXIDES: IARC - Group 2B.
_______ 4. FIRST AID MEASURES _______
If irritation or other symptoms (as noted above) occur or persist
from any route of exposure, remove the affected individual from the
area: see a physician/get medical attention.
Eye Contact
Immediately flush eyes with plenty of clean water for an extended
time, not less than five (5) minutes. Flush longer if there is any
indication of residual chemical in the eye.
Ensure adequate flushing of the eyes by separating the eyelids with
fingers and roll eyes in a circular motion.
Skin Contact
Wash the affected area thoroughly with plenty of water and soap.
Inhalation
If affected, remove to fresh air.
If not breathing, give artificial respiration.
See a physician.
Ingestion
No ingestion effects known. Treat symptomatically.
See a physician.
_______ 5. FIRE FIGHTING MEASURES _______
NFPA Flammability Class N/A
Flash Range > 212.F (100.C)
Explosive Range Not Applicable
Fire and Explosive Properties
This product is not known to present any fire hazard.
Extinguishing Media
Being an aqueous system, product is not a fire hazard, as supplied.
After water is evaporated, dry solids could burn. Water spray, ABC
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MATERIAL SAFETY DATA SHEET
Product Name: PERFORMAX* 8471
Document: PFX8471 CFLN: AUUS
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dry chemical and protein type air foams are effective. Carbon
dioxide may be ineffective on larger fires due to a lack of cooling
capacity, which may result in reignition.
Fire Fighting Instructions
Wear self-contained breathing apparatus (SCBA) equipped with a full
facepiece and operated in a pressure-demand mode (or other positive
pressure mode) and approved protective clothing. Personnel without
suitable respiratory protection must leave the area to prevent
significant exposure to hazardous gases from combustion, burning or
decomposition. In an enclosed or poorly ventilated area, wear SCBA
during cleanup immediately after a fire as well as during the attack
phase of firefighting operations.
Unusual Fire/Explosion Hazards
None known for the product as delivered (water solution).
Irritating and toxic substances will be emitted upon combustion,
burning or decomposition of the dry solids.
Closed container may rupture (due to build up in pressure) when
exposed to extreme heat.
_______ 6. ACCIDENTAL RELEASE MEASURES _______
Containment Techniques
Contain spill.
If spilled in an enclosed area, ventilate.
Clean-Up Techniques
Wear proper personal protective clothing and equipment.
Do not flush liquid into public sewer, water systems or surface
waters.
Recover as much as possible for reuse.
Soak up large spill residue and small spills with an inert absorbent.
Place into labeled, closed container; store in safe location to
await disposal.
Wash the spill area with soap and water.
Change contaminated clothing and launder before reuse.
CAUTION: Spilled liquid and dried film are slippery. Use care to
avoid falls.
_______ 7. HANDLING AND STORAGE _______
Handling
Avoid eye contact.
Avoid repeated or prolonged skin contact.
Avoid inhalation of aerosol, mist, spray, fume or vapor.
Avoid drinking, tasting, swallowing or ingesting this product.
Wash thoroughly after handling this product. Always wash up before
eating, smoking or using the facilities.
Provide eyewash fountains and safety showers in the work area.
Use under well-ventilated conditions.
Storage
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MATERIAL SAFETY DATA SHEET
Product Name: PERFORMAX* 8471
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Do not store in open, unlabeled or mislabeled containers.
Keep container closed when not in use.
Do not reuse empty container without commercial cleaning or
reconditioning.
_______ 8. EXPOSURE CONTROLS/PERSONAL PROTECTION _______
Occupational Exposure Limits
--ACGIH-TWA--- -ACGIH-STEL--- ---OSHA-TWA--- --OSHA-STEL---
Water
N/E N/E N/E N/E
Polymer/Solids
N/E N/E N/E N/E
Antimony oxide
N/E N/E N/E N/E
Decabromodiphenyl oxide
N/E N/E N/E N/E
Formaldehyde
N/E 0.30 PPM C 0.75 PPM 2.00 PPM
Notes:
Although ACGIH and OSHA have not established specific limits for
antimony oxide, they have established the following limits
for antimony compounds: ACGIH TWA = 0.5 mg/m3, OSHA TWA = 0.5 mg/m3.
Engineering Controls
Always provide effective general and, when necessary, local exhaust
ventilation to draw spray, aerosol, fume, mist and vapor away from
workers to prevent routine inhalation.
Ventilation must be adequate to maintain the ambient workplace
atmosphere below the exposure limit(s) outlined in the MSDS.
Ventilation guidelines/techniques may be found in publications such
as Industrial Ventilation: American Conference of Governmental
Industrial Hygienists, 1330 Kemper Meadow Drive, Cincinnati, OH,
45240-1634, USA.
Eye/Face Protection
Wear eye protection.
Skin Protection
Wear protective gloves.
Respiratory Protection
Wear a respirator approved by NIOSH/MSHA (e.g., an organic vapor
respirator, a full face air purifying respirator for organic vapors,
or a self-contained breathing apparatus) whenever exposure to aerosol,
mist, spray, fume or vapor exceed the exposure limit(s) of any
chemical substance listed in this MSDS.
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MATERIAL SAFETY DATA SHEET
Product Name: PERFORMAX* 8471
Document: PFX8471 CFLN: AUUS
Effective Date: 05 March 1999 Page Number: 5/9
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Use respirator in accordance with manufacturer's use limitations and
OSHA standard 1910.134 (29CFR).
_______ 9. PHYSICAL AND CHEMICAL PROPERTIES _______
Form Liquid
Appearance/Color Opaque, white
Odor Acrid
Solubility (in water) Dilutable
pH Value 9.0-9.5
Boiling Range > 212.F (100.C)
Vapor Pressure (mmHg) ~ 18. @ 68.F (20.C)
Melting Point Not Applicable
Evaporation Rate Slower than n-Butyl Acetate
Vapor Density Lighter than air
Partition Coefficient Not Applicable
% Volatile Weight 42%-48%
Specific Gravity 1.14-1.26
VOC <0.5%
_______ 10. STABILITY AND REACTIVITY _______
Stability
This product is stable
Hazardous Polymerization Hazardous polymerization will not occur
Conditions to Avoid
Do not freeze.
Incompatibility with other materials
No specific incompatibilities. Materials which are not compatible
with water will not be compatible with this product.
Substances that are not compatible with ordinary organic compounds
(such as strong oxidizers) will not be compatible with this product.
Contamination with strong acids and bases may coagulate latex.
Hazardous Decomposition Products
Carbon dioxide and carbon monoxide.
_______ 11. TOXICOLOGICAL INFORMATION _______
Route Species Exposure and Dose
Antimony oxide
Inhalation Rat, adult LC50 50. mg/m3
FORMALDEHYDE: Inhalation of formaldehyde at concentrations above 5
ppm for 6 hours a day for 2 years caused cancer in laboratory animals.
_______ 12. ECOLOGICAL INFORMATION _______
No ecological testing has been conducted on this product.
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MATERIAL SAFETY DATA SHEET
Product Name: PERFORMAX* 8471
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_______ 13. DISPOSAL CONSIDERATIONS _______
Incinerate waste product when in liquid form (i.e., as supplied) in a
properly permitted (approved) incineration facility in accordance
with federal, state and local regulations.
Liquids cannot be disposed of in a landfill.
Liquid product generally requires some pre-disposal treatment to
separate the liquid from the polymeric portion. Typically, this is
done by coagulating the polymer and removing the liquid. The liquid
portion may be discharged to an industrial or public treatment works
with approval of appropriate permitting authorities.
Solid products can be sent to an approved landfill, or preferably
incinerated.
As furnished to the purchaser, this product may contain sufficient
residual vinylidene chloride (listed by the EPA as
1,1-dichloroethylene) to exceed the Toxicity Characteristic Leaching
Procedure (TCLP) de minimus of 0.7 mg/l set by the U.S. EPA
(40CFR261.24). Hazardous waste number U078 under RCRA TCLP
regulations.
EPA: CERCLA RQ. Antimony oxide is 1000 lbs (454 kg)
EPA: CERCLA RQ. Arsenic is 1 lb. (0.454 kg). Arsenic is an
unavoidable by-product (0.3%) of antimony oxide.
_______ 14. TRANSPORTATION INFORMATION _______
UN Number N/A
UN Pack Group N/A
UN Class N/A
ICAO/IATA Class N/A
IMDG Class N/A
ADR/RID Class N/A
Notes:
For shipments exceeding the RQ (See Section 13):
Environmentally Hazardous Substance, Liquid, N.O.S. (Antimony
oxide), 9, UN 3082, PG III, R.Q.
Environmentally Hazardous Substance, Liquid, N.O.S. (contains
arsenic), 9, UN 3082, PG III, RQ.
_______ 15. REGULATORY INFORMATION _______
--SARA Title III Section 313----------
This product contains the following toxic chemicals subject to the
reporting requirements of Section 313 of the Emergency Planning and
Community Right-to-Know Act of 1986 and of 40 CFR 372:
Antimony oxide
Decabromodiphenyl oxide
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MATERIAL SAFETY DATA SHEET
Product Name: PERFORMAX* 8471
Document: PFX8471 CFLN: AUUS
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--SARA Title III Section 312 Hazard Category (40 CFR 311/312)--
Acute Health: No Release of Pressure: No
Chronic Health: No Reactive: No
Fire: No
--The following ingredients are registered for TSCA 12B--
Decabromodiphenyl oxide
--PROP 65 (Carcinogen)----------
WARNING: This product contains a chemical known to the state of
California to cause cancer.
Antimony oxide
Formaldehyde
Chemical identity of some or all components present is confidential
business information (trade secret) and is being withheld as permitted
by 29CFR1910.1200 (i).
US (Federal) Regulations
TSCA: All components of this product are either listed on the U.S.
Toxic Substances Control Act (TSCA) inventory of chemicals or are
otherwise compliant with TSCA regulations.
Clean Air Act (CAA): This product when processed may give off a CAA
substance (CAA section 112). The amount given off varies and is
dependent upon process conditions (i.e. use, curing, heating). Listed
below are possible CAA substances in this product:
Antimony compounds
Vinylidene chloride
Formaldehyde
International Regulations
Canadian DSL: All components in this product are on the Canadian
Domestic Substances List (DSL), on the Canadian Non-Domestic
Substances List (NDSL), or are exempt from listing.
Canadian Ingredient Disclosure List (WHMIS): Not applicable.
Canadian WHMIS: This product is NOT controlled under the Canadian
Workplace Hazardous Materials Information System (WHMIS).
_______ 16. OTHER INFORMATION _______
HMIS Rating (H-F-R-PPI) 2-0-0-B
NFPA Rating (H-F-R) 2-0-0
KEY: 0=Insignificant; 1=Slight; 2=Moderate; 3=High; 4=Extreme.
Hazardous Materials Identification System (HMIS), National Paint and
Coatings Assn. rating applies to product "as packaged" (i.e., ambient
temperature).
National Fire Protection Association (NFPA) rating identifies the
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MATERIAL SAFETY DATA SHEET
Product Name: PERFORMAX* 8471
Document: PFX8471 CFLN: AUUS
Effective Date: 05 March 1999 Page Number: 8/9
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severity of hazards of material during a fire emergency (i.e., "on
fire").
Other Information
FORMALDEHYDE: Workplace exposure to formaldehyde is regulated by
OSHA 1910.1048 (CFR Title 29). This regulation requires labeling if
the product is capable under its normally expected conditions of
handling, processing, and use of releasing enough formaldehyde to
result in airborne concentrations above 0.5 ppm. Laboratory
experiments simulating mixing or compounding of emulsions show that
the airborne concentration of formaldehyde is not likely to exceed
0.1 ppm (0.1 mg/kg) when residual formaldehyde is <0.009% (<90 ppm or
<90 mg/kg) in the wet emulsion. When the concentration in the wet
emulsion exceeds ~800 ppm (~800 mg/kg), the airborne concentration of
formaldehyde could exceed 0.5 ppm (0.5 mg/kg). Purchasers of this
product should not solely rely on BFGoodrich data, but should do
sufficient in-plant monitoring of formaldehyde levels to assure
compliance of their operations.
Legend:
*: A Trademark of The BFGoodrich Company
ACGIH: American Conference of Governmental Industrial Hygienists
A1: Confirmed human carcinogen
A2: Suspected human carcinogen
A3: Animal carcinogen
CAS No: Chemical Abstract Service Registry Number
IARC: International Agency for Research on Cancer
Group1: Carcinogenic to humans
Group2A: Probably carcinogenic to humans
Group2B: Possibly carcinogenic to humans
Group3: Unclassifiable as a carcinogen to humans
MSHA: Mine Safety and Health Administration
NIOSH: National Institute for Occupational Safety and Health
NTP: National Toxicology Program
N/A: Not Applicable
N/E: None Established
OSHA: Occupational Safety and Health Administration
PEL: Permissible Exposure Limit
PNOC: Particulates Not Otherwise Classified
RTK: Right To Know
STEL: Short Term Exposure Limit (15 minute Time Weighted Average)
TLV: Threshold Limit Value
C: Ceiling limit
S: Skin notation refers to the potential significant
contribution to the overall exposure by the cutaneous route
including mucous membranes and the eyes and by direct skin
contact with the substance
WEEL: Workplace Environmental Exposure Level
WHMIS: Canadian Workplace Hazardous Materials Information System
Users Responsibility/Disclaimer of Liability
As the conditions or methods of use are beyond our control, we do not
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MATERIAL SAFETY DATA SHEET
Product Name: PERFORMAX* 8471
Document: PFX8471 CFLN: AUUS
Effective Date: 05 March 1999 Page Number: 9/9
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assume any responsibility and expressly disclaim any liability for any
use of this material. Information contained herein is believed to be
true and accurate but all statements or suggestions are made without
warranty, expressed or implied, regarding accuracy of the information,
the hazards connected with the use of the material or the results to
be obtained from the use thereof. Compliance with all applicable
federal, state and local laws and local regulations remains the
responsibility of the user.
This bulletin cannot cover all possible situations which the user may
experience during processing. Each aspect of your operation should be
examined to determine if, or where, additional precautions may be
necessary. All health and safety information contained in this
bulletin should be provided to your employees or customers. It is
your responsibility to develop appropriate work practice guidelines
and employee instructional programs for your operation.
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