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* * * * * * * * * * * * * * * * * * * * * * * * * * * * * * M S D S * * * * Canadian Centre for Occupational Health and Safety * * * * * * * * * * * * * * * * Issue : 99-2 (May, 1999) * *** IDENTIFICATION *** MSDS RECORD NUMBER : 1966809 PRODUCT NAME(S) : PERFORMAX* 8471 PRODUCT IDENTIFICATION : Product Number: PFX8471 DATE OF MSDS : 1999-03-05 CURRENCY NOTE : This MSDS was provided to CCOHS in electronic form on 1999-03-31 *** MANUFACTURER INFORMATION *** MANUFACTURER : B F Goodrich ADDRESS : 9911 Brecksville Road Cleveland Ohio U.S.A. 44141-3247 Telephone: 800-331-1144 216-447-5000 EMERGENCY TELEPHONE NO. : 800-424-9300 (CHEMTREC, 24 Hour) *** SUPPLIER/DISTRIBUTOR INFORMATION *** SUPPLIER/DISTRIBUTOR : Goodrich Canada Inc ADDRESS : 100 Regina Street South, Suite 360 Waterloo Ontario Canada N2J 4P9 Telephone: 519-888-3330 Télécopieur : 519-888-3337 EMERGENCY TELEPHONE NO. : 613-996-6666 (CANUTEC, Transportation, Canada) 800-424-9300 (CHEMTREC, Transportation, USA) *** MATERIAL SAFETY DATA *** MATERIAL SAFETY DATA SHEET Product Name: PERFORMAX* 8471 Document: PFX8471 CFLN: AUUS Effective Date: 05 March 1999 Page Number: 1/9 -------------------------------------------------------------------------------- _______ 1. PRODUCT AND COMPANY IDENTIFICATION _______ Product Name PERFORMAX* 8471 Company Identification BFGoodrich Performance Materials 9911 Brecksville Rd. Cleveland, OH 44141-3247 Telephone (800) 331-1144 / (216) 447-5000 Chemtrec (24 Hour) (800) 424-9300 Preparer Health, Safety, and Environmental Department Product Description Flame retarding aqueous dispersion. _______ 2. COMPOSITION, INFORMATION ON INGREDIENTS _______ --Ingredient-- -CAS Number- ---%--- Water 0007732-18-5 < 46 Polymer/Solids Proprietary 39 Antimony oxide 0001309-64-4 < 7.9 Decabromodiphenyl oxide 0001163-19-5 7.7 Formaldehyde 0000050-00-0 < 0.060 Notes: Amounts specified are typical and do not represent a specification. _______ 3. HAZARDS IDENTIFICATION _______ Acute Health Effects Repeated or prolonged skin contact may cause irritation. Vapors or direct eye contact may cause irritation. Ingestion may cause irritation. Inhalation may cause irritation of the respiratory tract and mucous membranes. FORMALDEHYDE: Vapors may cause eye, nose, and throat irritation at levels below the STEL for some people. These symptoms are more noticeable as airborne concentrations increase. Chronic Health Effects FORMALDEHYDE: Prolonged,excessive, or repeated exposure to formaldehyde or solutions containing formaldehyde may cause an -------------------------------------------------------------------------------- MATERIAL SAFETY DATA SHEET Product Name: PERFORMAX* 8471 Document: PFX8471 CFLN: AUUS Effective Date: 05 March 1999 Page Number: 2/9 -------------------------------------------------------------------------------- allergic skin reaction and/or respiratory disorders (sensitization). Signs/Symptoms of Exposure Irritation. Routes of Exposure/Entry Eyes, skin contact, inhalation, ingestion. Target Organs Eyes, respiratory tract, skin. Medical Conditions Aggravated by Exposure Pre-existing skin problems may be aggravated by prolonged or repeated contact. Persons with sensitive airways (e.g., asthmatics) may react to vapors. Carcinogenic Status FORMALDEHYDE: IARC - Group 2A; NTP - Anticipated human carcinogen; OSHA - Regulated as a carcinogen; ACGIH - A2. ANTIMONY TRIOXIDES: IARC - Group 2B. _______ 4. FIRST AID MEASURES _______ If irritation or other symptoms (as noted above) occur or persist from any route of exposure, remove the affected individual from the area: see a physician/get medical attention. Eye Contact Immediately flush eyes with plenty of clean water for an extended time, not less than five (5) minutes. Flush longer if there is any indication of residual chemical in the eye. Ensure adequate flushing of the eyes by separating the eyelids with fingers and roll eyes in a circular motion. Skin Contact Wash the affected area thoroughly with plenty of water and soap. Inhalation If affected, remove to fresh air. If not breathing, give artificial respiration. See a physician. Ingestion No ingestion effects known. Treat symptomatically. See a physician. _______ 5. FIRE FIGHTING MEASURES _______ NFPA Flammability Class N/A Flash Range > 212.F (100.C) Explosive Range Not Applicable Fire and Explosive Properties This product is not known to present any fire hazard. Extinguishing Media Being an aqueous system, product is not a fire hazard, as supplied. After water is evaporated, dry solids could burn. Water spray, ABC -------------------------------------------------------------------------------- MATERIAL SAFETY DATA SHEET Product Name: PERFORMAX* 8471 Document: PFX8471 CFLN: AUUS Effective Date: 05 March 1999 Page Number: 3/9 -------------------------------------------------------------------------------- dry chemical and protein type air foams are effective. Carbon dioxide may be ineffective on larger fires due to a lack of cooling capacity, which may result in reignition. Fire Fighting Instructions Wear self-contained breathing apparatus (SCBA) equipped with a full facepiece and operated in a pressure-demand mode (or other positive pressure mode) and approved protective clothing. Personnel without suitable respiratory protection must leave the area to prevent significant exposure to hazardous gases from combustion, burning or decomposition. In an enclosed or poorly ventilated area, wear SCBA during cleanup immediately after a fire as well as during the attack phase of firefighting operations. Unusual Fire/Explosion Hazards None known for the product as delivered (water solution). Irritating and toxic substances will be emitted upon combustion, burning or decomposition of the dry solids. Closed container may rupture (due to build up in pressure) when exposed to extreme heat. _______ 6. ACCIDENTAL RELEASE MEASURES _______ Containment Techniques Contain spill. If spilled in an enclosed area, ventilate. Clean-Up Techniques Wear proper personal protective clothing and equipment. Do not flush liquid into public sewer, water systems or surface waters. Recover as much as possible for reuse. Soak up large spill residue and small spills with an inert absorbent. Place into labeled, closed container; store in safe location to await disposal. Wash the spill area with soap and water. Change contaminated clothing and launder before reuse. CAUTION: Spilled liquid and dried film are slippery. Use care to avoid falls. _______ 7. HANDLING AND STORAGE _______ Handling Avoid eye contact. Avoid repeated or prolonged skin contact. Avoid inhalation of aerosol, mist, spray, fume or vapor. Avoid drinking, tasting, swallowing or ingesting this product. Wash thoroughly after handling this product. Always wash up before eating, smoking or using the facilities. Provide eyewash fountains and safety showers in the work area. Use under well-ventilated conditions. Storage -------------------------------------------------------------------------------- MATERIAL SAFETY DATA SHEET Product Name: PERFORMAX* 8471 Document: PFX8471 CFLN: AUUS Effective Date: 05 March 1999 Page Number: 4/9 -------------------------------------------------------------------------------- Do not store in open, unlabeled or mislabeled containers. Keep container closed when not in use. Do not reuse empty container without commercial cleaning or reconditioning. _______ 8. EXPOSURE CONTROLS/PERSONAL PROTECTION _______ Occupational Exposure Limits --ACGIH-TWA--- -ACGIH-STEL--- ---OSHA-TWA--- --OSHA-STEL--- Water N/E N/E N/E N/E Polymer/Solids N/E N/E N/E N/E Antimony oxide N/E N/E N/E N/E Decabromodiphenyl oxide N/E N/E N/E N/E Formaldehyde N/E 0.30 PPM C 0.75 PPM 2.00 PPM Notes: Although ACGIH and OSHA have not established specific limits for antimony oxide, they have established the following limits for antimony compounds: ACGIH TWA = 0.5 mg/m3, OSHA TWA = 0.5 mg/m3. Engineering Controls Always provide effective general and, when necessary, local exhaust ventilation to draw spray, aerosol, fume, mist and vapor away from workers to prevent routine inhalation. Ventilation must be adequate to maintain the ambient workplace atmosphere below the exposure limit(s) outlined in the MSDS. Ventilation guidelines/techniques may be found in publications such as Industrial Ventilation: American Conference of Governmental Industrial Hygienists, 1330 Kemper Meadow Drive, Cincinnati, OH, 45240-1634, USA. Eye/Face Protection Wear eye protection. Skin Protection Wear protective gloves. Respiratory Protection Wear a respirator approved by NIOSH/MSHA (e.g., an organic vapor respirator, a full face air purifying respirator for organic vapors, or a self-contained breathing apparatus) whenever exposure to aerosol, mist, spray, fume or vapor exceed the exposure limit(s) of any chemical substance listed in this MSDS. -------------------------------------------------------------------------------- MATERIAL SAFETY DATA SHEET Product Name: PERFORMAX* 8471 Document: PFX8471 CFLN: AUUS Effective Date: 05 March 1999 Page Number: 5/9 -------------------------------------------------------------------------------- Use respirator in accordance with manufacturer's use limitations and OSHA standard 1910.134 (29CFR). _______ 9. PHYSICAL AND CHEMICAL PROPERTIES _______ Form Liquid Appearance/Color Opaque, white Odor Acrid Solubility (in water) Dilutable pH Value 9.0-9.5 Boiling Range > 212.F (100.C) Vapor Pressure (mmHg) ~ 18. @ 68.F (20.C) Melting Point Not Applicable Evaporation Rate Slower than n-Butyl Acetate Vapor Density Lighter than air Partition Coefficient Not Applicable % Volatile Weight 42%-48% Specific Gravity 1.14-1.26 VOC <0.5% _______ 10. STABILITY AND REACTIVITY _______ Stability This product is stable Hazardous Polymerization Hazardous polymerization will not occur Conditions to Avoid Do not freeze. Incompatibility with other materials No specific incompatibilities. Materials which are not compatible with water will not be compatible with this product. Substances that are not compatible with ordinary organic compounds (such as strong oxidizers) will not be compatible with this product. Contamination with strong acids and bases may coagulate latex. Hazardous Decomposition Products Carbon dioxide and carbon monoxide. _______ 11. TOXICOLOGICAL INFORMATION _______ Route Species Exposure and Dose Antimony oxide Inhalation Rat, adult LC50 50. mg/m3 FORMALDEHYDE: Inhalation of formaldehyde at concentrations above 5 ppm for 6 hours a day for 2 years caused cancer in laboratory animals. _______ 12. ECOLOGICAL INFORMATION _______ No ecological testing has been conducted on this product. -------------------------------------------------------------------------------- MATERIAL SAFETY DATA SHEET Product Name: PERFORMAX* 8471 Document: PFX8471 CFLN: AUUS Effective Date: 05 March 1999 Page Number: 6/9 -------------------------------------------------------------------------------- _______ 13. DISPOSAL CONSIDERATIONS _______ Incinerate waste product when in liquid form (i.e., as supplied) in a properly permitted (approved) incineration facility in accordance with federal, state and local regulations. Liquids cannot be disposed of in a landfill. Liquid product generally requires some pre-disposal treatment to separate the liquid from the polymeric portion. Typically, this is done by coagulating the polymer and removing the liquid. The liquid portion may be discharged to an industrial or public treatment works with approval of appropriate permitting authorities. Solid products can be sent to an approved landfill, or preferably incinerated. As furnished to the purchaser, this product may contain sufficient residual vinylidene chloride (listed by the EPA as 1,1-dichloroethylene) to exceed the Toxicity Characteristic Leaching Procedure (TCLP) de minimus of 0.7 mg/l set by the U.S. EPA (40CFR261.24). Hazardous waste number U078 under RCRA TCLP regulations. EPA: CERCLA RQ. Antimony oxide is 1000 lbs (454 kg) EPA: CERCLA RQ. Arsenic is 1 lb. (0.454 kg). Arsenic is an unavoidable by-product (0.3%) of antimony oxide. _______ 14. TRANSPORTATION INFORMATION _______ UN Number N/A UN Pack Group N/A UN Class N/A ICAO/IATA Class N/A IMDG Class N/A ADR/RID Class N/A Notes: For shipments exceeding the RQ (See Section 13): Environmentally Hazardous Substance, Liquid, N.O.S. (Antimony oxide), 9, UN 3082, PG III, R.Q. Environmentally Hazardous Substance, Liquid, N.O.S. (contains arsenic), 9, UN 3082, PG III, RQ. _______ 15. REGULATORY INFORMATION _______ --SARA Title III Section 313---------- This product contains the following toxic chemicals subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right-to-Know Act of 1986 and of 40 CFR 372: Antimony oxide Decabromodiphenyl oxide -------------------------------------------------------------------------------- MATERIAL SAFETY DATA SHEET Product Name: PERFORMAX* 8471 Document: PFX8471 CFLN: AUUS Effective Date: 05 March 1999 Page Number: 7/9 -------------------------------------------------------------------------------- --SARA Title III Section 312 Hazard Category (40 CFR 311/312)-- Acute Health: No Release of Pressure: No Chronic Health: No Reactive: No Fire: No --The following ingredients are registered for TSCA 12B-- Decabromodiphenyl oxide --PROP 65 (Carcinogen)---------- WARNING: This product contains a chemical known to the state of California to cause cancer. Antimony oxide Formaldehyde Chemical identity of some or all components present is confidential business information (trade secret) and is being withheld as permitted by 29CFR1910.1200 (i). US (Federal) Regulations TSCA: All components of this product are either listed on the U.S. Toxic Substances Control Act (TSCA) inventory of chemicals or are otherwise compliant with TSCA regulations. Clean Air Act (CAA): This product when processed may give off a CAA substance (CAA section 112). The amount given off varies and is dependent upon process conditions (i.e. use, curing, heating). Listed below are possible CAA substances in this product: Antimony compounds Vinylidene chloride Formaldehyde International Regulations Canadian DSL: All components in this product are on the Canadian Domestic Substances List (DSL), on the Canadian Non-Domestic Substances List (NDSL), or are exempt from listing. Canadian Ingredient Disclosure List (WHMIS): Not applicable. Canadian WHMIS: This product is NOT controlled under the Canadian Workplace Hazardous Materials Information System (WHMIS). _______ 16. OTHER INFORMATION _______ HMIS Rating (H-F-R-PPI) 2-0-0-B NFPA Rating (H-F-R) 2-0-0 KEY: 0=Insignificant; 1=Slight; 2=Moderate; 3=High; 4=Extreme. Hazardous Materials Identification System (HMIS), National Paint and Coatings Assn. rating applies to product "as packaged" (i.e., ambient temperature). National Fire Protection Association (NFPA) rating identifies the -------------------------------------------------------------------------------- MATERIAL SAFETY DATA SHEET Product Name: PERFORMAX* 8471 Document: PFX8471 CFLN: AUUS Effective Date: 05 March 1999 Page Number: 8/9 -------------------------------------------------------------------------------- severity of hazards of material during a fire emergency (i.e., "on fire"). Other Information FORMALDEHYDE: Workplace exposure to formaldehyde is regulated by OSHA 1910.1048 (CFR Title 29). This regulation requires labeling if the product is capable under its normally expected conditions of handling, processing, and use of releasing enough formaldehyde to result in airborne concentrations above 0.5 ppm. Laboratory experiments simulating mixing or compounding of emulsions show that the airborne concentration of formaldehyde is not likely to exceed 0.1 ppm (0.1 mg/kg) when residual formaldehyde is <0.009% (<90 ppm or <90 mg/kg) in the wet emulsion. When the concentration in the wet emulsion exceeds ~800 ppm (~800 mg/kg), the airborne concentration of formaldehyde could exceed 0.5 ppm (0.5 mg/kg). Purchasers of this product should not solely rely on BFGoodrich data, but should do sufficient in-plant monitoring of formaldehyde levels to assure compliance of their operations. Legend: *: A Trademark of The BFGoodrich Company ACGIH: American Conference of Governmental Industrial Hygienists A1: Confirmed human carcinogen A2: Suspected human carcinogen A3: Animal carcinogen CAS No: Chemical Abstract Service Registry Number IARC: International Agency for Research on Cancer Group1: Carcinogenic to humans Group2A: Probably carcinogenic to humans Group2B: Possibly carcinogenic to humans Group3: Unclassifiable as a carcinogen to humans MSHA: Mine Safety and Health Administration NIOSH: National Institute for Occupational Safety and Health NTP: National Toxicology Program N/A: Not Applicable N/E: None Established OSHA: Occupational Safety and Health Administration PEL: Permissible Exposure Limit PNOC: Particulates Not Otherwise Classified RTK: Right To Know STEL: Short Term Exposure Limit (15 minute Time Weighted Average) TLV: Threshold Limit Value C: Ceiling limit S: Skin notation refers to the potential significant contribution to the overall exposure by the cutaneous route including mucous membranes and the eyes and by direct skin contact with the substance WEEL: Workplace Environmental Exposure Level WHMIS: Canadian Workplace Hazardous Materials Information System Users Responsibility/Disclaimer of Liability As the conditions or methods of use are beyond our control, we do not -------------------------------------------------------------------------------- MATERIAL SAFETY DATA SHEET Product Name: PERFORMAX* 8471 Document: PFX8471 CFLN: AUUS Effective Date: 05 March 1999 Page Number: 9/9 -------------------------------------------------------------------------------- assume any responsibility and expressly disclaim any liability for any use of this material. Information contained herein is believed to be true and accurate but all statements or suggestions are made without warranty, expressed or implied, regarding accuracy of the information, the hazards connected with the use of the material or the results to be obtained from the use thereof. Compliance with all applicable federal, state and local laws and local regulations remains the responsibility of the user. This bulletin cannot cover all possible situations which the user may experience during processing. Each aspect of your operation should be examined to determine if, or where, additional precautions may be necessary. All health and safety information contained in this bulletin should be provided to your employees or customers. It is your responsibility to develop appropriate work practice guidelines and employee instructional programs for your operation. -------------------------------------------------------------------------------- Last Page