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National Office of Pollution Prevention
Table of Contents
Abstract
Summary
1. Introduction
2. Monitoring/Direct Measurement of Releases
3. Analytical Methods
4. Quality Assurance/Quality Control
5. Estimation of Releases
6. Reporting
7. Validation / Verification
Glossary of Terms and Acronyms
References
Bibliography
Appendix A: Standardized Release Reporting Template
Appendix B: Error Estimation
Appendix C: US EPA AP-42 Emission Factors
GUIDANCE DOCUMENT FOR REPORTING OF RELEASES FROM THE BASE METALS SMELTING SECTOR

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1. Introduction

1.1 Background

Environment Canada and Health Canada have joint responsibility for the effective management of substances declared toxic under the Canadian Environmental Protection Act (CEPA). This provides for actions, including regulations, relating to the quantity or concentration of a toxic substance that may be released in to the environment.

Responsibilities under CEPA include identifying substances that may be toxic and assessing them to determine whether they are toxic under Section 11 of CEPA. The following substances that have been deemed toxic under CEPA 1988 are relevant to the Base Metals Smelting Sector (BMSS):

  • lead

  • mercury

  • inorganic arsenic compounds

  • inorganic cadmium compounds

  • oxidic, sulphidic and soluble inorganic nickel compounds

  • polychlorinated biphenyls (PCBs)

  • polychlorinated dibenzodioxins (dioxins)

  • polychlorinated dibenzofurans (furans)

In May 1996, a multi-stakeholder Issue Table (IT) for the BMSS Strategic Options Process (SOP) was convened to identify and evaluate options and provide advice to the Ministers of Environment and Health. The BMSS IT held ten meetings between May 1996 and February 1997. The SOP culminated in the development of a Strategic Report (SOR)2.

The SOR outlines environmental concerns associated with the BMSS and advances recommendations aimed at preserving and enhancing the quality of the environment that is affected by these complexes. Ten recommendations that were developed by the multi- stakeholder Issue Table are available in the June 1997 report "Strategic Options for the Management of Toxic Substances from the Base Metals Smelting Sector". The Strategic Options recommendations were intended to facilitate the development of a level playing field of environmental standards and foster the concept of continual improvement in environmental performance by all companies in the Canadian BMSS.

While the SOR focused on the CEPA-toxics listed above, this report also includes guidance related to particulate matter and sulphur dioxide. The inclusion of these two pollutants is relevant as part of the Canadian Council of Ministers of the Environment (CCME) agreement to develop comprehensive Multi-pollutant Emissions Reduction Strategies3 (MERS) for some sectors, including the Base Metals Smelting sector. In addition, particulate matter has been assessed as CEPA-toxic4 and a notice of intent has been published to declare the principal substances that form airborne fine particulate matter (i.e., precursors)5 as toxic. Sulphur dioxide is amongst the list of precursors. In addition, sulphur dioxide is a major contributor to the problem of acid rain. Releases from primary and secondary copper smelters and refineries and releases from primary and secondary zinc smelters and refineries have also been declared CEPA-toxic. These releases contain varying amounts of numerous substances, but the key components are sulphur dioxide, metals (copper, zinc, nickel, lead, cadmium, chromium and arsenic) and particulate matter under 10 microns (PM10).

Many of the recommendations of the SOR including Recommendation # 1, "Release Reduction Targets and Schedules" require reliable, verifiable data. One step to ensure reliable, consistently reported data is the development of this Guidance Document for Reporting of Releases.

1.1.1 Existing Reporting Requirements

The Base Metals Smelting Sector is currently required to submit a number of reports on releases under federal and provincial legislation and as conditions of licences and permits.

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1.1.2 Development of Guidance Document for Reporting of Releases

Information on sampling and analysis techniques, emissions estimation and reporting practices was obtained through publicly available sources such as standard reference methods, guidance documents, papers and web sites.

Key documents used to develop this Guidance Document include:

  • Environment Canada Guide for Reporting to the National Pollutant Release Inventory 19996

  • ARET Participation Guide, Voluntary Action on Toxic Substances7

  • Mining Association of Canada Guide for Completing the National Pollutant Release Inventory (NPRI) in 20008

  • Mining Association of Canada Guidelines for Reporting ARET Data9

  • Ontario Ministry of the Environment, Step by Step Guideline for Emission Calculation, Record Keeping and Reporting for Airborne Contaminant Discharge10

  • Australia National Pollutant Inventory, Emissions Estimation Technique Manual for Nickel Concentrating, Smelting and Refining11

  • European Union, Integrated Pollution Prevention and Control (IPPC) Reference Document on Best Available Techniques in the Non Ferrous Metals Industries12

This information was supplemented with discussions with Environment Canada, provincial environmental authorities and industry personnel. Environment Canada personnel provided guidance on the structure of this report as well as information on Standard Reference Methods. Provincial representatives and industry personnel were informally polled to provide details on existing reporting requirements.

In addition to information from the Canadian BMSS, Hatch reviewed existing BMSS reporting standards, requirements and practices from the base metals smelting industry in Canada, the United States and other countries, such as Australia and from other relevant Canadian industrial sectors.

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1.2 Sector Description

The primary base metals smelting and refining sector is composed of producers of copper, lead, nickel, and zinc, with cadmium and cobalt as by-products. The majority of the feed material is from primary materials (i.e., concentrate), but some of the facilities included in this sector process secondary materials (e.g., recyclables).

As shown in Figure 1-1 base metals metallurgical complexes are located in British Columbia (1), Alberta (1), Manitoba (2), Ontario (5), Quebec (5) and New Brunswick (1).

Figure 1-1: Canadian Base Metals Smelting and Refining Sector
Figure 1-1: Canadian Base Metals Smelting and Refining Sector

Click to enlarge

Province

Company

Site/Location

Facility

Map #

British Columbia

Cominco

Trail

Lead Plant,
Zinc Plant

1

Alberta

Corefco/Sherritt

Fort Saskatchewan

Nickel & Cobalt Refinery

2

Manitoba

 

Hudson Bay

Flin Flon

Copper Smelter,
Zinc Plant

3

Inco

Thompson

Nickel Smelter,
Nickel Refinery

4

Ontario

 

 

 

 

Falconbridge

Kidd/Timmins

Copper Smelter,
Copper Refinery,
Zinc Plant

5

Falconbridge

Sudbury

Nickel/Copper Smelter

6

Inco

Copper Cliff/Sudbury

Nickel Copper Smelter,
Copper Refinery,
Nickel Refinery

7

Inco

Port Colborne

Cobalt Refinery

8

Tonolli

Mississauga

Secondary Lead Smelter

9

Quebec

 

 

 

 

Noranda

Horne/Rouyn-Noranda

Copper Smelter

10

Noranda

CEZ/Valleyfield

Zinc Plant

11

Noranda

CCR/Montreal

Copper Refinery

12

Nova Pb

Ville St. Catherine

Secondary Lead Smelter

13

Noranda

Gaspé/Murdochville

Copper Smelter

14

New Brunswick

Noranda

Brunswick/Belledune

Lead Plant

15

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2 Strategic Options for the Management of Toxic Substances from the Base Metals Smelting Sector Report of Stakeholders consultations, Environment Canada, June 23, 1997,
www.ec.gc.ca/toxics/docs/sor/bms/en/toc.cfm
.

3 Canadian Council of Ministers of Environment (CCME) website www.ccme.ca.

4 Environment Canada and Health Canada, Priority Substance List Assessment Report Respirable Particulate Matter Less Than or Equal to 10 Microns, May 2000.

5 Canada Gazette, Part I, Vol. 134 No 29, Saturday, July 15, 2000.

6 Environment Canada Guide for Reporting to the National Pollutant Release Inventory 1999, ISBN 0- 662-28338-4.

7 ARET Participation Guide, Voluntary Action on Toxic Substances.

8 Mining Association of Canada Guide for Completing the National Pollutant Release Inventory (NPRI) in 2000, Prepared by the Data Integrity Group, April 2000, www.mining.ca.

9 Mining Association of Canada Guidelines for Reporting ARET Data and Preparing ARET Action Plans in 2000, May 2000, Prepared by the Data Integrity Group, www.mining.ca.

10 Ontario Ministry of the Environment, Step by Step Guideline for Emission Calculation, Record Keeping and Reporting for Airborne Contaminant Discharge, November 2, 2000.

11 Australia National Pollutant Inventory, Emissions Estimation Technique Manual for Nickel Concentrating, Smelting and Refining, First published in June 1999, www.environment.gov.au/epg/npi/handbooks/.

12 European Commission, Integrated Pollution Prevention and Control (IPPC) Reference Document on Best Available Techniques in the Non Ferrous Metals Industries, May 2000, http://eippcb.jrc.es.

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