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National Office of Pollution Prevention
Table of Contents
Abstract
Summary
1. Introduction
2. Monitoring/Direct Measurement of Releases
3. Analytical Methods
4. Quality Assurance/Quality Control
5. Estimation of Releases
6. Reporting
7. Validation / Verification
Glossary of Terms and Acronyms
References
Bibliography
Appendix A: Standardized Release Reporting Template
Appendix B: Error Estimation
Appendix C: US EPA AP-42 Emission Factors
GUIDANCE DOCUMENT FOR REPORTING OF RELEASES FROM THE BASE METALS SMELTING SECTOR

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6. Reporting

The information on monitoring, analysis, quality assurance/quality control and release estimation provided in this Guidance Document can be used to calculate releases for reporting to existing federal or provincial programs or for internal company use.

From time to time, Environment Canada requests release data from the Base Metals Smelting Sector. This information was gathered during the Strategic Options Process in 1996 and an update of the data was requested in 2000.

This section focuses on reporting in response to a request for data from Environment Canada. A Standardized Release Reporting Template is found in Appendix A. This template is similar to the format used to collect data from the Base Metals Smelting Sector in 2000.

6.1 Reporting Entity

It is recommended that total releases be reported by facility as opposed to company-wide totals. This approach is consistent with NPRI.

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6.2 Data to be Reported

6.2.1 General Information

General information to be reported includes:

  • Facility Information (e.g., name, address, web site, NPRI ID#)

  • Contact Information (e.g, name, title, telephone number, fax number, e-mail address)

  • Production (e.g., products and by-products)

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6.2.2 Release Data

The total releases from the site should be reported including all releases including non-routine releases such as spills. Quantities of pollutant releases are usually quantified in Spill Reports made to provincial agencies. Air emission data should include both stack and fugitive releases.

In addition to the site-wide totals, information should be provided for each major release point. Release point data should include:

  • Total release from the release point

  • Method of estimating releases

  • Error Estimation - absolute, percent or degree (high to low)

  • Concentration - average and maximum

    • for stack data, conditions for concentration (temperature, static pressure in the off-gas duct, atmospheric pressure, moisture content etc.) should also be noted.
6.2.2.1 Reporting Units

It is recommended that releases of particulate matter, sulphur dioxide, arsenic, cadmium, lead and nickel be reported in tonnes.

Mercury releases should be reported in kilograms (kg) for consistency with NPRI.

Dioxins and furans should be reported in grams Toxic Equivalents (g TEQ)

Concentration in stack samples should be reported as milligrams per Normal cubic metre (mg/Nm3). Normal conditions are 25°C and 1 atmosphere.

Concentration in effluent samples should be reported as milligrams per litre (mg/L).

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6.2.2.2 Example of Reporting Template

An example for air releases from the Standardized Release Reporting Template is shown in Table 6-1. The full template is found in Appendix A.

Table 6-1: Example of Air Reporting Template
  Total Stack A Stack B Stack C Fugitive
Annual Release (tonne/yr)          
Estimation Method (M, C, E, O)          
Error Estimation (%)          
Average Stack Conc. (mg/Nm3)          
Max. Stack Concentration (mg/Nm3)          
Stack Flow Rate (Nm3/h)          

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6.3 Nomenclature

6.3.1 Estimation Method

It is recommended that facilities use the NPRI notation for indicating the method used for release estimation.

  • monitoring or direct measurement (Code M);

  • mass balance (Code C);

  • emission factors (Code E); and

  • engineering estimates (Code O).

A new code of "NI" was added to NPRI in 2000 only for dioxins/furans for instances when No Information is available.

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6.3.2 Low-Level Releases

The following notations are suggested for low-level releases:

  • <LMDL (less than the method detection limit) means that the facility has tested for a parameter and all results are lower than the analytical method detection limit;

  • n.m/e (not measured or estimated) means that the facility has not tested for or estimated the amount of pollutant; or

  • not significant indicates that the facility has not tested for a parameter but believes that the quantity of the parameter released is not significant.

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6.3.2.1 Less Than Detection Limit

Detection limits are defined in Section 3.4. When all analysis in a given year are less than the laboratory method detection limit, facilities should use the notation <≈LMDL.

When some samples are above the detection limit and others are less than the detection limit, it has been suggested that the samples be averaged assuming a value of the detection limit for samples that were analyzed as less than detection limit.

For example, if a facility took four water samples and tested for a parameter with a laboratory method detection limit of 0.01 mg/L. The four results might be:

<0.01 0.015 <0.01 0.02

The average would then be calculated assuming that the less than detection limit samples were valued at 0.01 to yield and average concentration of 0.01375 or rounded to 0.014 mg/L.

Another method is to assume a value of half of the detection limit for samples below the detection limit for averaging purposes. In this case the average concentration would be rounded to 0.011 mg/L.

The MAC Data Integrity Group is working on recommending a single method to calculate yearly loadings where there is a mixture of analysis values below and above the detection limit.

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6.3.2.2 Not Significant

If a facility reports that a release is not significant, it is recommended that the facility provide some technical background information to support this designation.

For example, there might be some analytical data which shows that the parameter is not present in the releases. Alternatively, some documentation might be available showing that the parameter is not present in the input streams.

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